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- W4230304563 abstract "A heterotetranuclear zinc(II)—cerium(IV) complex [(ZnL)2Ce(OAc)2][Ce(NO3)6]⋅Py (H2L = 6,6'-methoxy-2,2'-[1,2-ethylenedioxybis(nitrilomethylidyne)]diphenol and Py = pyridine) is successfully prepared by a one-pot reaction of a Salamo-type ligand H2L with Zn(OAc)2⋅2H2O, Ce(NO3)3⋅6H2O, and an auxiliary ligand Py. The ZnII—CeIV complex consists of one dicationic [(ZnL)2Ce(OAc)2]2+ unit with a deca-coordinated CeIV atom, one [Ce(NO3)6]2– dianionic unit with a dodeca-coordinated CeIV atom, and one uncoordinated Py molecule. Interestingly, the two CeIV atoms are positive tetravalent, which may probably be due to the oxidation of trivalent CeIII atoms during the reaction. Moreover, the photophysical properties of the ZnII—CeIV complex are studied." @default.
- W4230304563 created "2022-05-11" @default.
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- W4230304563 date "2019-01-01" @default.
- W4230304563 modified "2023-09-30" @default.
- W4230304563 title "A heterotetranuclear zinc(II)—cerium(IV) salamo complex possessing deca- and dodeca-coordinated cerium(IV) atoms: Synthesis, structure, and photophysical properties" @default.
- W4230304563 doi "https://doi.org/10.26902/jsc_id44167" @default.
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