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- W4230390876 abstract "Ungesättigt und doch luftstabil: Der dreifach koordinierte Rutheniumkomplex 2, der die Alkenepoxidierung hoch aktiv vermittelt und an der Luft recycliert werden kann, wurde auf SiO2 erhalten. Dabei wurde der p-Cymol-Ligand durch die exotherme Reaktion von O2 und Isobutyraldehyd (IBA) aus der Koordinationssphäre der gesättigten Vorstufe 1 verdrängt (Ru rot, Cl dunkelblau, N grün, S gelb, O blau, C grau, H weiß). Die direkte Aktivierung mit O2 ist dagegen Rechnungen zufolge endotherm." @default.
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- W4230390876 date "2007-09-24" @default.
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- W4230390876 title "Selective Formation of a Coordinatively Unsaturated Metal Complex at a Surface: A SiO2-Immobilized, Three-Coordinate Ruthenium Catalyst for Alkene Epoxidation" @default.
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- W4230390876 doi "https://doi.org/10.1002/ange.200700980" @default.
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