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- W4230441244 abstract "Copolymers containing water-soluble poly(ethylene glycol) (PEG) side chains and precisely controlled functional microstructures were synthesized by sequence-controlled copolymerization of donor and acceptor comonomers, that is, styrene derivatives and N-substituted maleimides. Two routes were compared for the preparation of these structures: a) the direct use of a PEG–styrene macromonomer as a donor comonomer, and b) the use of an alkyne-functionalized styrenic comonomer, which was PEGylated by copper-catalyzed alkyne–azide cycloaddition after polymerization. The latter method was found to be the most versatile and enabled the synthesis of high-precision copolymers. For example, PEGylated copolymers containing precisely positioned fluorescent (e.g. pyrene), switchable (e.g. azobenzene), and reactive functionalities (e.g. an activated ester) were prepared." @default.
- W4230441244 created "2022-05-11" @default.
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- W4230441244 creator A5069487479 @default.
- W4230441244 creator A5074434542 @default.
- W4230441244 date "2014-07-02" @default.
- W4230441244 modified "2023-10-18" @default.
- W4230441244 title "Precision PEGylated Polymers Obtained by Sequence-Controlled Copolymerization and Postpolymerization Modification" @default.
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- W4230441244 doi "https://doi.org/10.1002/ange.201403799" @default.
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