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- W4230588806 abstract "Kinetic isotope effects between H2O and D2O in HCOOH and CH3OH adsorption and oxidation on platinized Pt electrodes have been studied in sulphuric acid electrolyte. The normal kinetic effects have been found for CH3OH adsorption and for the oxidation of the chemisorbed species, the inverse isotope effect for HCOOH adsorption has been detected. The latter observation, as well as highly negative value of entropy of activation and the pH dependence, support the “reduction” mechanism of HCOOH adsorption described previously. Solvent isotope effects contribute to CH3OH as well as HCOOH adsorption. The observed low isotope effect for the oxidation of chemisorbed species is interpreted as an evidence that adsorbed water molecules are the very oxygen containing species involved in the oxidation." @default.
- W4230588806 created "2022-05-11" @default.
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- W4230588806 date "1977-05-25" @default.
- W4230588806 modified "2023-10-18" @default.
- W4230588806 title "Kinetic isotope effects between light and heavy water in HCOOH and CH3OH adsorption and oxidation on Pt mechanistic considerations" @default.
- W4230588806 doi "https://doi.org/10.1016/0368-1874(77)80171-8" @default.
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