Matches in SemOpenAlex for { <https://semopenalex.org/work/W4230736210> ?p ?o ?g. }
- W4230736210 endingPage "7226" @default.
- W4230736210 startingPage "7223" @default.
- W4230736210 abstract "Abstract An intensely luminescent gold(I)–silver(I) cluster [(C)(AuPPhpy 2 ) 6 Ag 6 (CF 3 CO 2 ) 3 ](BF 4 ) 5 (PPhpy 2 =bis(2‐pyridyl)phenylphosphine) ( 3 ) is synthesized by the reaction of [(C)(AuPPhpy 2 ) 6 Ag 4 ](BF 4 ) 6 with AgCF 3 CO 2 . All eight faces of the octahedral C@Au 6 core in 3 are capped, that is, six faces are capped by silver ions and two by tetrafluoroborates. Cluster 3 is intensely luminescent in solution with a quantum yield of 92 %. Ligation of CF 3 CO 2 − ions is vital for the construction and emission properties of 3 , as confirmed by DFT calculations. BF 4 − ions are involved in the protecting sphere of the metal core, as evidenced by 19 F NMR data. The participation of phosphines, CF 3 CO 2 − , and BF 4 − ions in the protection of the emissive core and the enhancement of the rigidity of the cluster result in the high emission efficiency. This is the first example of organic ligands and inorganic anions forming a rigid protecting sphere for luminescent coinage‐metal clusters." @default.
- W4230736210 created "2022-05-11" @default.
- W4230736210 creator A5017887421 @default.
- W4230736210 creator A5019134089 @default.
- W4230736210 creator A5075110917 @default.
- W4230736210 creator A5084707324 @default.
- W4230736210 date "2017-05-03" @default.
- W4230736210 modified "2023-09-25" @default.
- W4230736210 title "Full Protection of Intensely Luminescent Gold(I)-Silver(I) Cluster by Phosphine Ligands and Inorganic Anions" @default.
- W4230736210 cites W1970805443 @default.
- W4230736210 cites W1981184997 @default.
- W4230736210 cites W1981615236 @default.
- W4230736210 cites W1986356528 @default.
- W4230736210 cites W1998814101 @default.
- W4230736210 cites W1998945486 @default.
- W4230736210 cites W1999828149 @default.
- W4230736210 cites W2001310886 @default.
- W4230736210 cites W2001826704 @default.
- W4230736210 cites W2004123744 @default.
- W4230736210 cites W2010350673 @default.
- W4230736210 cites W2020834630 @default.
- W4230736210 cites W2032500472 @default.
- W4230736210 cites W2033805304 @default.
- W4230736210 cites W2041103943 @default.
- W4230736210 cites W2054653999 @default.
- W4230736210 cites W2064150867 @default.
- W4230736210 cites W2074363977 @default.
- W4230736210 cites W2076471388 @default.
- W4230736210 cites W2086791656 @default.
- W4230736210 cites W2088042081 @default.
- W4230736210 cites W2100777240 @default.
- W4230736210 cites W2116934581 @default.
- W4230736210 cites W2133144571 @default.
- W4230736210 cites W2141437836 @default.
- W4230736210 cites W2147298597 @default.
- W4230736210 cites W2158282769 @default.
- W4230736210 cites W2159462626 @default.
- W4230736210 cites W2159898933 @default.
- W4230736210 cites W2313833942 @default.
- W4230736210 cites W2328781319 @default.
- W4230736210 cites W2329385807 @default.
- W4230736210 cites W2332039025 @default.
- W4230736210 cites W2511592115 @default.
- W4230736210 cites W4211217538 @default.
- W4230736210 cites W4211240100 @default.
- W4230736210 cites W4229677838 @default.
- W4230736210 cites W4231418810 @default.
- W4230736210 cites W4243424460 @default.
- W4230736210 cites W4243919599 @default.
- W4230736210 cites W4249416922 @default.
- W4230736210 doi "https://doi.org/10.1002/ange.201702522" @default.
- W4230736210 hasPublicationYear "2017" @default.
- W4230736210 type Work @default.
- W4230736210 citedByCount "22" @default.
- W4230736210 countsByYear W42307362102017 @default.
- W4230736210 countsByYear W42307362102018 @default.
- W4230736210 countsByYear W42307362102019 @default.
- W4230736210 countsByYear W42307362102020 @default.
- W4230736210 countsByYear W42307362102022 @default.
- W4230736210 crossrefType "journal-article" @default.
- W4230736210 hasAuthorship W4230736210A5017887421 @default.
- W4230736210 hasAuthorship W4230736210A5019134089 @default.
- W4230736210 hasAuthorship W4230736210A5075110917 @default.
- W4230736210 hasAuthorship W4230736210A5084707324 @default.
- W4230736210 hasConcept C11111787 @default.
- W4230736210 hasConcept C115624301 @default.
- W4230736210 hasConcept C121332964 @default.
- W4230736210 hasConcept C145148216 @default.
- W4230736210 hasConcept C148869448 @default.
- W4230736210 hasConcept C161790260 @default.
- W4230736210 hasConcept C164866538 @default.
- W4230736210 hasConcept C171001562 @default.
- W4230736210 hasConcept C178790620 @default.
- W4230736210 hasConcept C179104552 @default.
- W4230736210 hasConcept C181817918 @default.
- W4230736210 hasConcept C185592680 @default.
- W4230736210 hasConcept C192562407 @default.
- W4230736210 hasConcept C198819137 @default.
- W4230736210 hasConcept C199164860 @default.
- W4230736210 hasConcept C199360897 @default.
- W4230736210 hasConcept C2777716191 @default.
- W4230736210 hasConcept C2778402489 @default.
- W4230736210 hasConcept C41008148 @default.
- W4230736210 hasConcept C49040817 @default.
- W4230736210 hasConcept C544153396 @default.
- W4230736210 hasConcept C62520636 @default.
- W4230736210 hasConcept C75473681 @default.
- W4230736210 hasConcept C8010536 @default.
- W4230736210 hasConcept C91881484 @default.
- W4230736210 hasConceptScore W4230736210C11111787 @default.
- W4230736210 hasConceptScore W4230736210C115624301 @default.
- W4230736210 hasConceptScore W4230736210C121332964 @default.
- W4230736210 hasConceptScore W4230736210C145148216 @default.
- W4230736210 hasConceptScore W4230736210C148869448 @default.
- W4230736210 hasConceptScore W4230736210C161790260 @default.
- W4230736210 hasConceptScore W4230736210C164866538 @default.
- W4230736210 hasConceptScore W4230736210C171001562 @default.
- W4230736210 hasConceptScore W4230736210C178790620 @default.