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- W4230774630 abstract "Die Phosphinsäureazide des Typs R2P(X)N3 mit R = Me und Et und X = O und S bilden farblose bis schwach gelbe, nicht explosive, monomere Verbindungen. Aus der Diskussion der Schwingungs- und NMR-Spektren folgt bei den Thiophosphinsäureaziden eine PS Einfachbindung, während bei den Oxoverbindungen eine PO Doppelbindung angenommen werden kann. Aus den Massenspektren geht hervor, daß nur die Oxoverbindungen eine Alkylgruppe einfangen. Dialkylphosphinsäureazide The phosphonylazides of the type R2P(X)N3 with R = Me, Et and X = O, S form colourless to light yellow, not explosive, monomeric compounds. The vibrational and NMR spectra are discussed. So the bond order of the PS bond is nearly one in opposition to the PO double bond. Only the mass spectra of the oxo-compounds show the capture of an alkyl group." @default.
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- W4230774630 date "1975-12-01" @default.
- W4230774630 modified "2023-09-24" @default.
- W4230774630 title "Dialkylphosphins�ureazide" @default.
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- W4230774630 doi "https://doi.org/10.1002/zaac.19754180308" @default.
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