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- W4230778827 abstract "Publisher SummaryThis chapter discusses the related materials of silicates. A few silicates are known in which there are simple, discrete orthosilicate, SiO44- anions. In such components, the associated cations are coordinated by the oxygen atoms and various structures are found depending on the coordination number of the cations. The simplest of the condensed silicate anions are formed by combining two or more SiO4 tetrahedra by sharing oxygen atoms. The pyrosilicate anion is present in thortveitite and hemimorphite. When SiO4 tetrahedra are linked into infinite two-dimensional networks, the empirical formula for the anions is (SiO52-)n. Many silicates have sheet structures with sheets bound together by cations that lie between them. The next extension in the progression from simple SiO44- ions to larger and more complex structures is to three-dimensional structures in which oxygen is shared between two tetrahedra. The empirical formula for such a substance is simply (SiO2)n. However, if some silicon atoms in such a three-dimensional framework structure are replaced by aluminium, the frame must be negatively charged and neutralized by cations. Aluminosilicates of these types are clays and many zeolites." @default.
- W4230778827 created "2022-05-11" @default.
- W4230778827 date "1995-01-01" @default.
- W4230778827 modified "2023-09-23" @default.
- W4230778827 title "Chapter 7 Related materials: Silicates" @default.
- W4230778827 doi "https://doi.org/10.1016/s0167-2991(06)81515-6" @default.
- W4230778827 hasPublicationYear "1995" @default.
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