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• W4230778859 startingPage "6369" @default.
• W4230778859 abstract "Abstract Polyolefins that contain polar functional groups are important materials for next‐generation lightweight engineering thermoplastics. Post‐polymerization modification is an ideal method for the incorporation of polar groups into branched polyolefins; however, it typically results in chain scission events, which have deleterious effects on polymer properties. Herein, we report a metal‐free method for radical‐mediated C−H xanthylation that results in the regioselective functionalization of branched polyolefins without coincident polymer‐chain scission. This method enables a tunable degree of polymer functionalization and capitalizes on the versatility of the xanthate functional group to unlock a wide variety of C−H transformations previously inaccessible on branched polyolefins." @default.
• W4230778859 created "2022-05-11" @default.
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• W4230778859 creator A5061951111 @default.
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• W4230778859 date "2018-04-23" @default.
• W4230778859 modified "2023-09-24" @default.
• W4230778859 title "Regioselective C−H Xanthylation as a Platform for Polyolefin Functionalization" @default.
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• W4230778859 doi "https://doi.org/10.1002/ange.201803020" @default.
• W4230778859 hasPublicationYear "2018" @default.
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