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- W4231008967 abstract "[[216496-49-0] BC36CuH40N6 (MW 630.36) InChI = 1S/C36H40BN6.Cu/c1-22-16-25(4)34(26(5)17-22)31-10-13-41(38-31)37(42-14-11-32(39-42)35-27(6)18-23(2)19-28(35)7)43-15-12-33(40-43)36-29(8)20-24(3)21-30(36)9;/h10-21,37H,1-9H3;/q-1;+1 InChIKey = QYOVOYWYRXQXPU-UHFFFAOYSA-N (reagent used in the catalytic transfer of carbene, from diazo compounds, and nitrene, from iminoiodinanes, groups) Solubility: soluble in most common organic solvents, partially soluble in hexane. Preparation: this complex is prepared by the direct reaction of CuI and TlTpMs in methylene chloride.1 One mmol of the copper salt was reacted with 1 equiv of the thallium salt of the homoscorpionate ligand.2 The resulting suspension, containing a yellow-greenish solid of thallium iodide, was stirred for 8 h, filtered, and the resulting colorless solution was evaporated under reduced pressure to give the desired complex as a white solid in 80–90% yield. Purification: the crude solid obtained as described above can be crystallized from saturated methylene chloride-hexane solutions upon cooling at −20 °C overnight. White microcrystalline material of analytical purity was collected in 85% yield. Handling, Storage, and Precautions: this complex is stable toward atmospheric oxygen in the solid state, but somewhat unstable when dissolved in organic solvents." @default.
- W4231008967 created "2022-05-11" @default.
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- W4231008967 date "2007-03-15" @default.
- W4231008967 modified "2023-10-17" @default.
- W4231008967 title "{Hydrotris(3-(2,4,6-trimethylphenyl))pyrazolylborate}copper, TpMsCu" @default.
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- W4231008967 doi "https://doi.org/10.1002/047084289x.rn00686" @default.
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