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- W4231025052 abstract "Publisher SummaryThis chapter discusses several kinetic models for solid state reactions. The geometric models of solid state reactions are based upon the processes of nucleation and growth of product nuclei by interface advance. Nuclei are generated predominantly, perhaps exclusively, at or near crystal surfaces and the numbers participating at different times have been measured for some decompositions using microscopy. Several models for nucleus generation are single-step nucleation, instantaneous nucleation, linear nucleation, multi-step nucleation, and branching nucleation. In decompositions of solids where the initiation of reaction results in the rapid development of a large number of closely-spaced growth nuclei on all surfaces or on specific crystallographic faces, the overall kinetics of reaction are determined by the geometry of advance of a coherent reaction interface from these boundaries towards the centres of the reactant particles. In reactions of this type, the induction period, if any, may be too short to permit detection, and during this time, there is virtually instantaneous and dense nucleation across all active surfaces. The kinetics of a first-order reaction is very similar to those represented by the contracting volume equation, except in the final stages of reaction when α approaches 1.00." @default.
- W4231025052 created "2022-05-11" @default.
- W4231025052 date "1999-01-01" @default.
- W4231025052 modified "2023-10-05" @default.
- W4231025052 title "Chapter 3 Kinetic models for solid state reactions" @default.
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- W4231025052 doi "https://doi.org/10.1016/s0167-6881(99)80004-4" @default.
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