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- W4231122031 abstract "This chapter deals with the conversion of aromatic compounds to dihydroaromatic compounds by the action of alkali metals in liquid ammonia; polynuclear compounds are emphasized. Various aromatic compounds are classified according to the principal intermediate that persists in ammonia solution. Possibilities include (1) radical anions, (2) dianions, and (3) monoanions; monoanions are formed by the ammonia protonation of dianions. Most two-, three-, and four-ring compounds fit into the monoanion category, including naphthalene, biphenyl, anthracene, and terphenyl. The regioselectivity of this reaction is also discussed, and computational methods such as MNDO (semi-empirical molecular orbital calculations) are used to predict products by a determination of the positions of highest electron density in the intermediate dianions. Finally, competing processes such as dimerization and bond cleavage are considered." @default.
- W4231122031 created "2022-05-11" @default.
- W4231122031 creator A5018872647 @default.
- W4231122031 date "1987-12-22" @default.
- W4231122031 modified "2023-09-26" @default.
- W4231122031 title "Dissolving-Metal Reduction of Polynuclear Aromatic Compounds in Liquid Ammonia" @default.
- W4231122031 doi "https://doi.org/10.1021/ba-1988-0217.ch005" @default.
- W4231122031 hasPublicationYear "1987" @default.
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