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- W4231145067 abstract "Standard rate constants (ks)ms and cathodic transfer coefficients (αc)ms of the electrode reaction of Cr(III)CyDTA/Cr(II)CyDTA have been obtained by the coulostatic method in methanol + water, ethanol + water, n-propanol + water and n-butanol + water mixtures, where CyDTA means trans-1,2-cyclohexanediaminetetraacetate. The values of (ks)ms obtained at low concentrations of the alcohols are nearly equal to that obtained in aqueous solutions. With increasing concentrations of alcohols, they decrease, in the cases of methanol and n-butanol, in the concentration ranges in which the measurements were made, while, in the cases of ethanol and n-propanol, they decrease to reach minima at certain concentrations and then increase again. The values of (αc)ms obtained at high concentrations of n-propanol and n-butanol are much larger than those obtained in aqueous solutions." @default.
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- W4231145067 date "1975-11-10" @default.
- W4231145067 modified "2023-09-26" @default.
- W4231145067 title "Studies on the electrode reaction of Cr(III)CyDTA/Cr(II)CyDTA by the coulostatic method in various alcohol+water mixtures" @default.
- W4231145067 doi "https://doi.org/10.1016/s0022-0728(75)80160-4" @default.
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