Matches in SemOpenAlex for { <https://semopenalex.org/work/W4231330334> ?p ?o ?g. }
Showing items 1 to 65 of
65
with 100 items per page.
- W4231330334 abstract "<p>We describe here the carbonylative Murai reaction applied to 2-formylfurans, 2-formylpyrrols and 2-formylthiophenes. Thanks to the installation of removable imine directing groups, this acylation reaction takes place regioselectively at C3 position of the heterocyclopentadienes. It can be achieved by treating the two reaction partners with a catalytic amount of Ru<sub>3</sub>(CO)<sub>12</sub>, in toluene at 120-150 °C, after CO bubbling, at atmospheric pressure. DFT computations of the full catalytic cycle help in deciphering the mechanism of this transformation, and to rationalize the different behaviors depending on the nature of imine directing groups.</p>" @default.
- W4231330334 created "2022-05-12" @default.
- W4231330334 creator A5028353513 @default.
- W4231330334 creator A5043940764 @default.
- W4231330334 creator A5046772276 @default.
- W4231330334 creator A5055624429 @default.
- W4231330334 creator A5057623443 @default.
- W4231330334 creator A5058311858 @default.
- W4231330334 date "2019-12-17" @default.
- W4231330334 modified "2023-10-17" @default.
- W4231330334 title "Ru-Catalyzed Carbonylative Murai Reaction: Directed C3-Acylation of Biomass-Derived 2-Formyl Heteroaromatics" @default.
- W4231330334 doi "https://doi.org/10.26434/chemrxiv.11342096.v1" @default.
- W4231330334 hasPublicationYear "2019" @default.
- W4231330334 type Work @default.
- W4231330334 citedByCount "0" @default.
- W4231330334 crossrefType "posted-content" @default.
- W4231330334 hasAuthorship W4231330334A5028353513 @default.
- W4231330334 hasAuthorship W4231330334A5043940764 @default.
- W4231330334 hasAuthorship W4231330334A5046772276 @default.
- W4231330334 hasAuthorship W4231330334A5055624429 @default.
- W4231330334 hasAuthorship W4231330334A5057623443 @default.
- W4231330334 hasAuthorship W4231330334A5058311858 @default.
- W4231330334 hasBestOaLocation W42313303341 @default.
- W4231330334 hasConcept C121332964 @default.
- W4231330334 hasConcept C153294291 @default.
- W4231330334 hasConcept C155647269 @default.
- W4231330334 hasConcept C161790260 @default.
- W4231330334 hasConcept C178790620 @default.
- W4231330334 hasConcept C185592680 @default.
- W4231330334 hasConcept C193557335 @default.
- W4231330334 hasConcept C200239111 @default.
- W4231330334 hasConcept C21951064 @default.
- W4231330334 hasConcept C2776573223 @default.
- W4231330334 hasConcept C2778142098 @default.
- W4231330334 hasConcept C63338738 @default.
- W4231330334 hasConceptScore W4231330334C121332964 @default.
- W4231330334 hasConceptScore W4231330334C153294291 @default.
- W4231330334 hasConceptScore W4231330334C155647269 @default.
- W4231330334 hasConceptScore W4231330334C161790260 @default.
- W4231330334 hasConceptScore W4231330334C178790620 @default.
- W4231330334 hasConceptScore W4231330334C185592680 @default.
- W4231330334 hasConceptScore W4231330334C193557335 @default.
- W4231330334 hasConceptScore W4231330334C200239111 @default.
- W4231330334 hasConceptScore W4231330334C21951064 @default.
- W4231330334 hasConceptScore W4231330334C2776573223 @default.
- W4231330334 hasConceptScore W4231330334C2778142098 @default.
- W4231330334 hasConceptScore W4231330334C63338738 @default.
- W4231330334 hasLocation W42313303341 @default.
- W4231330334 hasLocation W42313303342 @default.
- W4231330334 hasLocation W42313303343 @default.
- W4231330334 hasOpenAccess W4231330334 @default.
- W4231330334 hasPrimaryLocation W42313303341 @default.
- W4231330334 hasRelatedWork W2152422399 @default.
- W4231330334 hasRelatedWork W2276818262 @default.
- W4231330334 hasRelatedWork W2325193303 @default.
- W4231330334 hasRelatedWork W2327991298 @default.
- W4231330334 hasRelatedWork W2616509386 @default.
- W4231330334 hasRelatedWork W2793943608 @default.
- W4231330334 hasRelatedWork W2951036786 @default.
- W4231330334 hasRelatedWork W2951321727 @default.
- W4231330334 hasRelatedWork W2952435304 @default.
- W4231330334 hasRelatedWork W4224300009 @default.
- W4231330334 isParatext "false" @default.
- W4231330334 isRetracted "false" @default.
- W4231330334 workType "article" @default.