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- W4231721000 abstract "[36896-63-6] C8H11AlS (MW 166.22) InChI = 1S/C6H6S.2CH3.Al/c7-6-4-2-1-3-5-6;;;/h1-5,7H;2*1H3;/q;;;+1/p-1 InChIKey = OKDMDDDFDCMSSS-UHFFFAOYSA-M (reagent used as a source of nucleophilic phenylthiolate in a wide array of reactions) Solubility: soluble in CH2Cl2, THF, hexane, and benzene. Form Supplied in: generated in situ from commercially available materials. Preparative Methods: to a solution of thiophenol (0.26 g, 2.4 mmol) in CH2Cl2 (2 mL) is added trimethylaluminum (1.0 M solution in hexane, 2.4 mL, 2.4 mmol) at 0 °C under argon. This mixture is kept at 0 °C for 20 min, and then additional reactants are added.1 Purification: Me2AlSPh can be generated, isolated as a solid, and recrystallized from pentane to form colorless plates of polymeric Me2AlSPh.2 Handling, Storage, and Precautions: Me2AlSPh should be generated and handled under an inert gas atmosphere. Stock solutions of this reagent can be stored under refrigeration for long time periods.3 Use of a fume hood is highly recommended." @default.
- W4231721000 created "2022-05-12" @default.
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- W4231721000 date "2003-04-15" @default.
- W4231721000 modified "2023-10-09" @default.
- W4231721000 title "Dimethylaluminum Phenylthiolate" @default.
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- W4231721000 doi "https://doi.org/10.1002/047084289x.rn00247" @default.
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