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- W4231741660 abstract "Abstract Multiple active individual molecular ruthenium catalysts have been pinpointed within growing polynorbornene, thereby revealing information on the reaction dynamics and location that is unavailable through traditional ensemble experiments. This is the first single‐turnover imaging of a molecular catalyst by fluorescence microscopy and allows detection of individual monomer reactions at an industrially important molecular ruthenium ring‐opening metathesis polymerization (ROMP) catalyst under synthetically relevant conditions (e.g. unmodified industrial catalyst, ambient pressure, condensed phase, ca. 0.03 m monomer). These results further establish the key fundamentals of this imaging technique for characterizing the reactivity and location of active molecular catalysts even when they are the minor components." @default.
- W4231741660 created "2022-05-12" @default.
- W4231741660 creator A5004332193 @default.
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- W4231741660 date "2017-09-25" @default.
- W4231741660 modified "2023-10-16" @default.
- W4231741660 title "Single Turnover at Molecular Polymerization Catalysts Reveals Spatiotemporally Resolved Reactions" @default.
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- W4231741660 doi "https://doi.org/10.1002/ange.201708284" @default.
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