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- W4231838839 abstract "Differential capacity-potential curves for a (111) face of silver in contact with aqueous solutions of the electrolytes NaF, NaClO4 and KPF6 have been analyzed. From the dependence of the potential of the capacity minimum on electrolyte concentration, it is found that the ionic specific adsorption decreases as: ClO−4 > F− > PF−6 ⩾ 0 The contributions of the interaction terms involved in the specific adsorption are discussed, taking into account results obtained previously for the (110) and (100) faces, and those for mercury. In particular, it is proposed that the stronger water-metal interactions for silver than those for mercury could be responsible for the absence of specific adsorption at the potential of zero charge (pzc) for the hexafluorophosphate ion on the three low-index faces. The potential of the capacity minimum can therefore be identified with the pzc. The pzc for the Ag (111)/aqueous electrolyte interface without specific adsorption is: −0.695 ± 0.005 V (SCE). The electrical double-layer model in the absence of specific adsorption accounts for the capacity-potential curves at different concentrations for the Ag (111)/KPF6 system in most of the electrode charge range, taking into account only the superficial roughness. In contrast, application of this model round the pzc requires a correction of the measured capacity for the crystalline heterogeneity due to surface defects. Estimates for the water-silver interactions are proposed for the (110), (100) and (111) faces. Ag (111) would be almost as hydrophilic as gallium." @default.
- W4231838839 created "2022-05-12" @default.
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- W4231838839 date "1989-09-01" @default.
- W4231838839 modified "2023-09-27" @default.
- W4231838839 title "Double layer on silver single crystal electrodes in contact with electrolytes having anions which are slightly specifically adsorbed" @default.
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- W4231838839 doi "https://doi.org/10.1016/0022-0728(89)80112-3" @default.
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