Matches in SemOpenAlex for { <https://semopenalex.org/work/W4231851556> ?p ?o ?g. }
Showing items 1 to 72 of
72
with 100 items per page.
- W4231851556 abstract "Enantiodivergence is an important concept in asymmetric catalysis that enables access to both enantiomers of a product relying on the same chiral source as reagent. This strategy is particularly appealing as an alternate approach when only one enantiomer of the required chiral ligand is readily accessible but both enantiomers of the product are desired. Despite the potential significance, general catalytic methods to effectively reverse enantioselectivity by changing an achiral reaction parameter remain underdeveloped. Herein we report our studies focused on elucidating the origin of metal-controlled enantioselectivity reversal in Lewis acid-catalysed Michael additions. Rigorous experimental and computational investigations reveal that specific interactions between the substrate and ligand depending on the choice of metal catalyst are a key factor responsible for the observed enantiodivergence. This holds potential to further our understanding of and facilitate the design of future enantiodivergent transformations." @default.
- W4231851556 created "2022-05-12" @default.
- W4231851556 creator A5024273464 @default.
- W4231851556 creator A5034853042 @default.
- W4231851556 creator A5039728719 @default.
- W4231851556 creator A5049025148 @default.
- W4231851556 creator A5059219075 @default.
- W4231851556 date "2021-04-15" @default.
- W4231851556 modified "2023-09-28" @default.
- W4231851556 title "Origin of Enantioselectivity Reversal in Lewis Acid-Catalysed Michael Additions Relying on the Same Chiral Source" @default.
- W4231851556 doi "https://doi.org/10.26434/chemrxiv.12386081.v3" @default.
- W4231851556 hasPublicationYear "2021" @default.
- W4231851556 type Work @default.
- W4231851556 citedByCount "0" @default.
- W4231851556 crossrefType "posted-content" @default.
- W4231851556 hasAuthorship W4231851556A5024273464 @default.
- W4231851556 hasAuthorship W4231851556A5034853042 @default.
- W4231851556 hasAuthorship W4231851556A5039728719 @default.
- W4231851556 hasAuthorship W4231851556A5049025148 @default.
- W4231851556 hasAuthorship W4231851556A5059219075 @default.
- W4231851556 hasBestOaLocation W42318515561 @default.
- W4231851556 hasConcept C111368507 @default.
- W4231851556 hasConcept C116569031 @default.
- W4231851556 hasConcept C127313418 @default.
- W4231851556 hasConcept C146686406 @default.
- W4231851556 hasConcept C161790260 @default.
- W4231851556 hasConcept C163638829 @default.
- W4231851556 hasConcept C170493617 @default.
- W4231851556 hasConcept C178790620 @default.
- W4231851556 hasConcept C185592680 @default.
- W4231851556 hasConcept C19927201 @default.
- W4231851556 hasConcept C21951064 @default.
- W4231851556 hasConcept C2777289219 @default.
- W4231851556 hasConcept C2780337600 @default.
- W4231851556 hasConcept C40875361 @default.
- W4231851556 hasConcept C486523 @default.
- W4231851556 hasConcept C55493867 @default.
- W4231851556 hasConcept C71240020 @default.
- W4231851556 hasConceptScore W4231851556C111368507 @default.
- W4231851556 hasConceptScore W4231851556C116569031 @default.
- W4231851556 hasConceptScore W4231851556C127313418 @default.
- W4231851556 hasConceptScore W4231851556C146686406 @default.
- W4231851556 hasConceptScore W4231851556C161790260 @default.
- W4231851556 hasConceptScore W4231851556C163638829 @default.
- W4231851556 hasConceptScore W4231851556C170493617 @default.
- W4231851556 hasConceptScore W4231851556C178790620 @default.
- W4231851556 hasConceptScore W4231851556C185592680 @default.
- W4231851556 hasConceptScore W4231851556C19927201 @default.
- W4231851556 hasConceptScore W4231851556C21951064 @default.
- W4231851556 hasConceptScore W4231851556C2777289219 @default.
- W4231851556 hasConceptScore W4231851556C2780337600 @default.
- W4231851556 hasConceptScore W4231851556C40875361 @default.
- W4231851556 hasConceptScore W4231851556C486523 @default.
- W4231851556 hasConceptScore W4231851556C55493867 @default.
- W4231851556 hasConceptScore W4231851556C71240020 @default.
- W4231851556 hasLocation W42318515561 @default.
- W4231851556 hasLocation W42318515562 @default.
- W4231851556 hasOpenAccess W4231851556 @default.
- W4231851556 hasPrimaryLocation W42318515561 @default.
- W4231851556 hasRelatedWork W15562827 @default.
- W4231851556 hasRelatedWork W17599941 @default.
- W4231851556 hasRelatedWork W21396956 @default.
- W4231851556 hasRelatedWork W30828221 @default.
- W4231851556 hasRelatedWork W32762970 @default.
- W4231851556 hasRelatedWork W36027279 @default.
- W4231851556 hasRelatedWork W37254406 @default.
- W4231851556 hasRelatedWork W6280080 @default.
- W4231851556 hasRelatedWork W7553445 @default.
- W4231851556 hasRelatedWork W8543845 @default.
- W4231851556 isParatext "false" @default.
- W4231851556 isRetracted "false" @default.
- W4231851556 workType "article" @default.