FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4231892581> ?p ?o ?g. }

• W4231892581 endingPage "783" @default.
• W4231892581 startingPage "730" @default.
• W4231892581 abstract "Desulfurization of fuel oils is an essential process employed in petroleum refineries to reduce the sulfur content to levels mandated for environmental protection. Hydrodesulfurization (HDS), which is currently being employed, is limited in treating refractory organosulfur compounds and only reduces the sulfur content in fuels to a range of 200-500 ppmS. In this chapter, several scientific and technological advances reported in the literature for the desulfurization of fuels are reviewed and discussed. Amongst these techniques, oxidative desulfurization (ODS) and adsorptive desulfurization (ADS) are proposed as additional steps to complement HDS in meeting the mandated ultra-low sulfur levels (10 ppmS). In the ODS technique, refractory organosulfur compounds are oxidized to organosulfones, followed by solvent extraction or adsorption of the organosulfones. The chemistry involved in the development and fabrication of sulfur/sulfone responsive adsorbents is also discussed. The use of molecular imprinted polymers (MIPs) and coordination polymers (CPs) for the selective adsorption of organosulfone compounds (in ODS) and/or organosulfur (in ADS) offers various properties such as imprinting effect, hydrogen bonding, π-π interactions, van der Waals forces, π-complexation, and electrostatic interactions. CPs, in particular metal organic frameworks (MOFs), have been reported to possess suitable features to overcome most of these challenges associated with adsorptive ultra-deep desulfurization when design strategies to achieve good selectivity are strictly followed. Matching the sizes of the cavities to the critical dimensions of the sulfur containing compounds (SCCs), using suitable metal centres which allow for coordinative interaction with the SCCs and using linkers with suitable functionality as to enhance specific interaction (dispersion forces) with the SCCs were considered to be pivotal features to prioritize. The prospects for the use of MIPs and CPs for future industrial applications in desulfurization are envisaged." @default.
• W4231892581 created "2022-05-12" @default.
• W4231892581 creator A5018392575 @default.
• W4231892581 creator A5060793298 @default.
• W4231892581 creator A5066326614 @default.
• W4231892581 date "2021-01-01" @default.
• W4231892581 modified "2023-09-26" @default.
• W4231892581 title "Coordination Polymers and Polymer Nanofibers for Effective Adsorptive Desulfurization" @default.
• W4231892581 cites W133352569 @default.
• W4231892581 cites W139515640 @default.
• W4231892581 cites W164993757 @default.
• W4231892581 cites W1823833522 @default.
• W4231892581 cites W1940354522 @default.
• W4231892581 cites W1963616577 @default.
• W4231892581 cites W1964934100 @default.
• W4231892581 cites W1965143950 @default.
• W4231892581 cites W1967257017 @default.
• W4231892581 cites W1968465142 @default.
• W4231892581 cites W1969605890 @default.
• W4231892581 cites W1972659765 @default.
• W4231892581 cites W1973813627 @default.
• W4231892581 cites W1974380511 @default.
• W4231892581 cites W1974831978 @default.
• W4231892581 cites W1974983982 @default.
• W4231892581 cites W1976804584 @default.
• W4231892581 cites W1977292876 @default.
• W4231892581 cites W1978862186 @default.
• W4231892581 cites W1978909398 @default.
• W4231892581 cites W1978966212 @default.
• W4231892581 cites W1979038727 @default.
• W4231892581 cites W1980704616 @default.
• W4231892581 cites W1982249293 @default.
• W4231892581 cites W1982838180 @default.
• W4231892581 cites W1983360028 @default.
• W4231892581 cites W1983703816 @default.
• W4231892581 cites W1983954358 @default.
• W4231892581 cites W1985090581 @default.
• W4231892581 cites W1985824512 @default.
• W4231892581 cites W1986218282 @default.
• W4231892581 cites W1988302704 @default.
• W4231892581 cites W1988465753 @default.
• W4231892581 cites W1988749831 @default.
• W4231892581 cites W1988998921 @default.
• W4231892581 cites W1989968127 @default.
• W4231892581 cites W1991572692 @default.
• W4231892581 cites W1991824586 @default.
• W4231892581 cites W1992279376 @default.
• W4231892581 cites W1992687359 @default.
• W4231892581 cites W1993573305 @default.
• W4231892581 cites W1993909755 @default.
• W4231892581 cites W1995104137 @default.
• W4231892581 cites W1996799603 @default.
• W4231892581 cites W1999071793 @default.
• W4231892581 cites W1999136678 @default.
• W4231892581 cites W1999347518 @default.
• W4231892581 cites W2000643890 @default.
• W4231892581 cites W2000969801 @default.
• W4231892581 cites W2001431804 @default.
• W4231892581 cites W2002130112 @default.
• W4231892581 cites W2003294457 @default.
• W4231892581 cites W2003541136 @default.
• W4231892581 cites W2005877813 @default.
• W4231892581 cites W2006404753 @default.
• W4231892581 cites W2007082361 @default.
• W4231892581 cites W2007894622 @default.
• W4231892581 cites W2008743407 @default.
• W4231892581 cites W2013111311 @default.
• W4231892581 cites W2013574159 @default.
• W4231892581 cites W2013630735 @default.
• W4231892581 cites W2014239685 @default.
• W4231892581 cites W2014241785 @default.
• W4231892581 cites W2014254639 @default.
• W4231892581 cites W2014723499 @default.
• W4231892581 cites W2015369431 @default.
• W4231892581 cites W2015528135 @default.
• W4231892581 cites W2015908192 @default.
• W4231892581 cites W2016194429 @default.
• W4231892581 cites W2016537932 @default.
• W4231892581 cites W2017294860 @default.
• W4231892581 cites W2021941585 @default.
• W4231892581 cites W2025012426 @default.
• W4231892581 cites W2028283748 @default.
• W4231892581 cites W2028960222 @default.
• W4231892581 cites W2032492324 @default.
• W4231892581 cites W2033309567 @default.
• W4231892581 cites W2034694643 @default.
• W4231892581 cites W2035903750 @default.
• W4231892581 cites W2037580701 @default.
• W4231892581 cites W2040417290 @default.
• W4231892581 cites W2043272676 @default.
• W4231892581 cites W2043737771 @default.
• W4231892581 cites W2043999541 @default.
• W4231892581 cites W2045017212 @default.
• W4231892581 cites W2047288490 @default.
• W4231892581 cites W2048835763 @default.
• W4231892581 cites W2049160711 @default.
• W4231892581 cites W2049220162 @default.
• W4231892581 cites W2049476513 @default.

• next