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• W4231924633 endingPage "9238" @default.
• W4231924633 startingPage "9234" @default.
• W4231924633 abstract "Abstract Herein, we report the employment of the MoMo quintuple bonded amidinate complex to stabilize Group 10 metal fragments {(Et 3 P) 2 M} (M=Pd, Pt) and give rise to the isolation of the unprecedented δ complexes. X‐ray analysis unambiguously revealed short contacts between Pd or Pt and two Mo atoms and a slight elongation of the MoMo quintuple bond in these two compounds. Computational studies show donation of the MoMo quintuple‐bond δ electrons to an empty σ orbital on Pd or Pt, and back‐donation from a filled Pd or Pt d π orbital into the MoMo δ* level (LUMO), consistent with the Dewar–Chatt–Duncanson model." @default.
• W4231924633 created "2022-05-12" @default.
• W4231924633 creator A5031933494 @default.
• W4231924633 creator A5050538257 @default.
• W4231924633 creator A5053858392 @default.
• W4231924633 creator A5079412631 @default.
• W4231924633 date "2015-06-26" @default.
• W4231924633 modified "2023-10-18" @default.
• W4231924633 title "The MoMo Quintuple Bond as a Ligand to Stabilize Transition-Metal Complexes" @default.
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• W4231924633 doi "https://doi.org/10.1002/ange.201504414" @default.
• W4231924633 hasPublicationYear "2015" @default.
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