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- W4232036701 abstract "The reduction of hydroxylamine by Cu+ ions, produced in 0.5 M H2SO4 solution by reaction of Cu2+ with copper powder has been investigated. The reaction is first order with respect to both reagents; the reaction products were found to be divalent copper ion and ammonia in equimolecular ratio. The intermediate formation of NH2 radical was shown on the basis of aniline detection among the products obtained carrying out the reaction in the presence of benzene. The value of k1 at 25°C is 5.1×10−4 l mol−1 s−1; activation parameters at 25°C are ΔH++=16.2 kcal mol−1 and ΔS++=−4 cal mol−1 K−1." @default.
- W4232036701 created "2022-05-12" @default.
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- W4232036701 date "1975-02-25" @default.
- W4232036701 modified "2023-09-26" @default.
- W4232036701 title "Kinetic study of the reduction of hydroxylamine by Cu(I)" @default.
- W4232036701 doi "https://doi.org/10.1016/0368-1874(75)85027-1" @default.
- W4232036701 hasPublicationYear "1975" @default.
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