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- W42320782 abstract "This dissertation presents a model capable of predicting equilibrium oil droplet contact angles on a solid surface immersed in surfactant solution, a thorough discussion of the effects of surfactant concentration and salt addition on contact angles, and an experimental investigation into the impact of voltage application to the solid surface on oil droplet shape in an aqueous/organic/solid system. The work contained in this dissertation resulted in five journal articles and numerous presentations. The model applies current theories of surfactant self-assembly, the quasi-chemical approximation for solid surface adsorption, and various aqueous/organic/solid system properties to determine organic droplet contact angles. The computational methodology employed by the model requires the description of the aqueous/organic/solid system by selected component balances and through numerical techniques determines the equilibrium component distribution and the organic droplet contact angle for the specific system. Results from the model are compared to experimental contact angle data for various surfactants, surfactant concentrations, salt concentrations, and surface materials. The investigation into the effects of low magnitude applied voltage on droplet phenomena and oil removal determined that significant changes in droplet shape and removal efficiency can occur for voltages between ±3.0 volts. These changes in droplet shape where then compared to observed improvements in ultrasonic oil removal from metal surfaces in aqueous solutions. Employing the theoretical understanding of aqueous/organic/solid systems a discussion of controlling phenomena and mechanisms was presented." @default.
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- W42320782 date "2004-01-01" @default.
- W42320782 modified "2023-09-24" @default.
- W42320782 title "Prediction of Organic Droplet Behavior on a Solid Surface as Influenced by Aqueous Surfactant Solutions" @default.
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