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- W4232108001 abstract "Abstract A highly convergent strategy for the synthesis of the natural product (−)‐rubriflordilactone B, and the proposed structure of (−)‐ pseudo ‐rubriflordilactone B, is described. Late stage coupling of diynes containing the respective natural product FG rings with a common AB ring aldehyde precedes rhodium‐catalyzed [2+2+2] alkyne cyclotrimerization to form the natural product skeleton, with the syntheses completed in just one further operation. This work resolves the uncertainty surrounding the identity of pseudo ‐rubriflordilactone B and provides a robust platform for further synthetic and biological investigations." @default.
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- W4232108001 date "2019-10-31" @default.
- W4232108001 modified "2023-10-15" @default.
- W4232108001 title "Convergent Total Syntheses of (−)‐Rubriflordilactone B and (−)‐ <i>pseudo</i> ‐Rubriflordilactone B" @default.
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- W4232108001 doi "https://doi.org/10.1002/ange.201908917" @default.
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