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- W4232149178 abstract "Bis-nitroxide malonate methanofullerene (NO)2-MF was studied as a biomimetic model of reduction–oxidation activity with natural compounds—cytochrome c (cyt c), dihydroquercetin (DHQ), ascorbic acid (AA) and synthetic drug—1-(β-oxyethyl)-4,6-dimethyl-1,2-dihydro-2-oxopyrimidine (xymedon®).(NO)2-MF may be used as the component of Langmuir monolayers on an aqueous subphase and as the adsorbate on silica gel. The activity of (NO)2-MF in the reaction with cyt c was compared with the effect of nitroxide species such as gaseous nitric oxide, 2,2,6,6-tetramethylpiperidine-1-oxyl radical (TEMPO) by using UV–vis and EPR-spectra. It has been shown, that iron(III) in cyt c3+ under action (NO)2-MF was reduced up to iron(II), similar effect was observed under the influence of gaseous NO in aqueous solution, but reduction of iron(III) in heme cyt c was reversible in the presence of TEMPO. Therefore, the state of Fe-heme in cyt c can be used as the indicator of the interaction of cyt c with nitroxide species in vitro.The interaction of cyt c, DHQ, xymedon® with (NO)2-MF monolayers was confirmed by the increasing of limiting area А0 from 0.88 nm2 up to 1.70 nm2 of (NO)2-MF on the aqueous subphase, by the paramagnetism and UV–vis spectral data changes. These results can be explained by appearance of oxoammonium ion (NO+)2-MF adlayers and monolayers.The antioxidant and regenerating effects were shown when treating wounds by xymedon® in the presence of additives (0.001%) of (NO)2-MF in the experiments on the rats." @default.
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- W4232149178 date "1984-01-01" @default.
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- W4232149178 title "A program to solve a set of linear coupled differential equations describing a collison process with several electronic and vibrational degrees of freedom" @default.
- W4232149178 doi "https://doi.org/10.1016/s0010-4655(84)82955-0" @default.
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