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- W4232183386 abstract "The diffusion coefficients of actinides and rare earths in liquid Cd are the inevitable constants to analyse kinetically the pyrometallurgical reprocessing of spent metal fuels. In this study, the diffusion coefficients of U in liquid Cd were measured electrochemically in LiCl-KCl-1.6 wt% UCl3 melts at 738, 773 and 823 K to be 1.7 × 10−5, 1.9 × 10−5 and 2.3 × 10−5 cm2 s−1, respectively. The activation energy was evaluated from the temperature dependence of the diffusion coefficients to be 17 kJ mol−1. It was found that the diffusion coefficient and activation energy correlated with the partial molar excess Gibbs energy." @default.
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- W4232183386 date "2014-05-11" @default.
- W4232183386 modified "2023-10-13" @default.
- W4232183386 title "Electrochemical Measurement of Diffusion Coefficient of U in Liquid Cd" @default.
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- W4232183386 doi "https://doi.org/10.1002/9781118448847.ch6l" @default.
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