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- W4232372306 abstract "A series of carbonyl-based homogeneous catalyst precursors has been prepared. These species include: Fe(CO){sub 4}PPh{sub 3}, Fe(CO){sub 3}(PPh{sub 3}){sub 2}, Fe(CO){sub 2}(PPh{sub 3}){sub 2}CS{sub 2}, S{sub 2}Fe{sub 2}(CO){sub 6}, S{sub 2}Fe{sub 3}(CO){sub 9}. Fe(CO){sub 4}PPh{sub 3} was prepared by a combined photochemical and thermal route from triphenylphosphine (PPh{sub 3}) in iron pentacarbonyl (Fe(CO){sub 5}). This preparation procedure, which is selective to the monosubstituted product, is outlined herein. Currently these compounds are being tested as catalysts/catalyst precursors with coal or model compounds in the tubing bomb reactors to provide information relating catalytic activity to catalyst structure and properties. (VC)" @default.
- W4232372306 created "2022-05-12" @default.
- W4232372306 creator A5041032543 @default.
- W4232372306 date "1991-09-11" @default.
- W4232372306 modified "2023-09-25" @default.
- W4232372306 title "Design, synthesis, and characterization of novel fine-particle, unsupported catalysts for coal liquefaction" @default.
- W4232372306 doi "https://doi.org/10.2172/5163577" @default.
- W4232372306 hasPublicationYear "1991" @default.
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