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- W4232439158 abstract "The synthesis of six novel zinc (II) mono(N-heterocyclic carbene) complexes is described. 1,3-Bis(mesityl)-imidazol-2-ylidene was reacted with the zinc salts ZnX2 (X=Cl, CH3COO, PhCOO, and PhCH2COO) to yield the corresponding monomeric Zn–NHC complex ZnCl2(NHC)(THF) (1) and dimeric [Zn(OOCCH3)2(NHC)]2 (2), [Zn(OOCPh)2(NHC)]2 (3), [Zn(OOCCH2Ph)2(NHC)]2 (4) (NHC=1,3-bis(mesityl)-imidazol-2-ylidene). Reaction of 1 with 2 equivalents of silver trifluoromethanesulfonate yielded monomeric Zn(O3SCF3)2(NHC)(THF) (5), reaction of 1 with sodium {[R(+)-α-2-(1-phenyl-ethylimino)-methyl]-phenolate} yielded monomeric ZnCl(OC6H4-2-CHN(CHPhCH3)(NHC) (6). Compounds 1, 4–6 were structurally characterized by X-ray analysis. Selected compounds were investigated for their activity in the copolymerization of carbon dioxide with cyclohexene oxide as well as in the ring-opening polymerization of cyclohexene oxide and ε-caprolactone." @default.
- W4232439158 created "2022-05-12" @default.
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- W4232439158 date "2004-06-01" @default.
- W4232439158 modified "2023-09-30" @default.
- W4232439158 title "N-heterocyclic carbene complexes of Zn(II): synthesis, X-ray structures and reactivity*1" @default.
- W4232439158 doi "https://doi.org/10.1016/s0022-328x(04)00242-6" @default.
- W4232439158 hasPublicationYear "2004" @default.
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