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• W4232528315 abstract "Abstract The synthesis and single‐crystal X‐ray structural characterization of the first endohedral metallofullerene to contain a heptagon in the carbon cage are reported. The carbon framework surrounding the planar LaSc 2 N unit in LaSc 2 N@C s (hept)‐C 80 consists of one heptagon, 13 pentagons, and 28 hexagons. This cage is related to the most abundant I h ‐C 80 isomer by one Stone–Wales‐like, heptagon/pentagon to hexagon/hexagon realignment. DFT computations predict that LaSc 2 N@C s (hept)‐C 80 is more stable than LaSc 2 N@D 5h ‐ C 80 , and suggests that the low yield of the heptagon‐containing endohedral fullerene may be caused by kinetic factors." @default.
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• W4232528315 date "2014-11-24" @default.
• W4232528315 modified "2023-10-07" @default.
• W4232528315 title "Synthesis and Structure of LaSc₂N@<i>C_s</i>(hept)-C₈₀with One Heptagon and Thirteen Pentagons" @default.
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• W4232528315 doi "https://doi.org/10.1002/ange.201409094" @default.
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