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- W4232627224 abstract "The title compound, C 26 H 32 O 11 , is composed of an α,β-unsaturated cyclohexanone ring ( A ), two cyclohexane rings ( B and C ), a six-membered lactone ring ( D ) and tetrahydrofuran ring ( E ). Ring A exists in a half-chair conformation with a C atom displaced by 0.679 (2) Å from the mean plane through the remaining five atoms. Ring B exists in a normal chair conformation. Both rings C and D exist in a twisted-chair conformation due to the O-atom bridge and the carbonyl group in rings C and D , respectively. Ring E shows an envelope conformation with a C atom displaced by 0.761 (1) Å from the mean plane through the remaining five atoms. The ring junctions are A / B trans , B / C trans , C / D cis and D / E cis . An intramolecular O—H...O hydrogen bond occurs. In the crystal, O—H...O hydrogen bonds involving the hydroxy, lactone and ester groups and C—H...O interactions are observed." @default.
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- W4232627224 date "2012-05-02" @default.
- W4232627224 modified "2023-10-16" @default.
- W4232627224 title "Brusatol" @default.
- W4232627224 doi "https://doi.org/10.1107/s1600536812018582" @default.
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