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- W4232803187 abstract "Despite recent progress in the catalytic transformation of inert phenol derivatives as alternatives to aryl halides and triflates, attempts at the cross-coupling of inert phenol derivatives with the C-H bonds of arenes have met with limited success. Herein, we report the rhodium-catalyzed cross-coupling of aryl carbamates with arenes bearing a convertible directing group. The key to success is the use of an in situ generated rhodium bis(N-heterocyclic carbene) species as the catalyst, which can promote activation of the inert C(sp2 )-O bond in aryl carbamates." @default.
- W4232803187 created "2022-05-12" @default.
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- W4232803187 creator A5049915510 @default.
- W4232803187 date "2017-01-09" @default.
- W4232803187 modified "2023-09-29" @default.
- W4232803187 title "C−O Activation by a Rhodium Bis(N-Heterocyclic Carbene) Catalyst: Aryl Carbamates as Arylating Reagents in Directed C−H Arylation" @default.
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- W4232803187 doi "https://doi.org/10.1002/anie.201610409" @default.
- W4232803187 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/28066977" @default.
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