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- W4233249511 abstract "Abstract The synthesis of hierarchically mesoporous polymers with multiple functionalities is challenging. Herein we reported a template‐free strategy for synthesis of phenolic azo‐polymers with hierarchical porous structures based on diazo‐coupling reaction in aqueous solution under mild conditions. The resultant polymers have surface areas up to 593 m 2 g −1 with the mesopore ratio of >80 %, and a good ability to complex with metal ions, such as Cu 2+ , Zn 2+ ,Ni 2+ , achieving a metal loading up to 26.24 wt %. Moreover, the polymers complexed with Zn showed excellent performance for catalyzing the reaction of CO 2 with epoxide, affording a TOF of 2570 h −1 in the presence of tetrabutyl ammonium bromide (7.2 mol %). The polymer complexed with Cu could catalyze the oxidation of alcohol with high efficiency." @default.
- W4233249511 created "2022-05-12" @default.
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- W4233249511 date "2016-05-20" @default.
- W4233249511 modified "2023-10-17" @default.
- W4233249511 title "Hierarchically Mesoporous<i>o</i>-Hydroxyazobenzene Polymers: Synthesis and Their Applications in CO<sub>2</sub>Capture and Conversion" @default.
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- W4233249511 doi "https://doi.org/10.1002/ange.201602667" @default.
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