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- W4233293723 abstract "The dissolution kinetics of three plagioclase feldspars (An13, An46, and An76) were studied in flow-through reactors over the pH range 3–7. In accordance with the surface complexation model, dissolution rate was described by the equation Rate= xaA exp(EakT)(CsH)n), where (Chs) is the concentration of protonated surface sites, xa is the mole fraction of these that are activated, A is the Arrhenius pre-exponential factorand Ea is the activation energy for the reaction. The reaction order with respect to surface charge (n) at pH < 5 is a function of mineral composition, and increases with increasing anorthite content. Orders of 0.46, 1.2, and 2.0 are obtained for oligoclase, andesine, and bytownite, respectively. This indicates that the reaction intermediate is more highly protonated in feldspars of higher aluminum content. The nonintegral reaction orders obtained demonstrate the importance of several surface species in the dissolution reaction.Reaction rates increase with increasing anorthite content. In acid solution this reflects the linear dependence of Ea on the number of Al-O-Si bonds involved in the rate-determining step. Under conditions of low surface protonation (in near-neutral solutions), dissolution is independent of surface charge. As reaction occurs at neutral alumina sites, the rate is approximately proportional to the anorthite (Al) content of the feldspar." @default.
- W4233293723 created "2022-05-12" @default.
- W4233293723 date "1998-01-01" @default.
- W4233293723 modified "2023-09-25" @default.
- W4233293723 title "Electroless nickel additive" @default.
- W4233293723 doi "https://doi.org/10.1016/s0026-0576(97)80273-5" @default.
- W4233293723 hasPublicationYear "1998" @default.
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