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• W4233350165 endingPage "11987" @default.
• W4233350165 startingPage "11983" @default.
• W4233350165 abstract "The thermally stable [(tBuMe2Si)2M] (M=Zn, Hg) generate R3Si. radicals in the presence of [(dmpe)Pt(PEt3)2] at 60–80 °C. The reaction proceeds via hexacoordinate Pt complexes, (M=Zn (2 a and 2 b), M=Hg (3 a and 3 b)) which were isolated and characterized. Mild warming or photolysis of 2 or 3 lead to homolytic dissociation of the PtMSiR3 bond generating silyl radicals and novel unstable pentacoordinate platinum paramagnetic complexes (M=Zn (5), Hg (6)) whose structures were determined by EPR spectroscopy and DFT calculations." @default.
• W4233350165 created "2022-05-12" @default.
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• W4233350165 date "2015-08-18" @default.
• W4233350165 modified "2023-10-16" @default.
• W4233350165 title "Activation of Homolytic SiZn and SiHg Bond Cleavage, Mediated by a Pt0Complex, via Novel PtZn and PtHg Compounds" @default.
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• W4233350165 doi "https://doi.org/10.1002/ange.201505805" @default.
• W4233350165 hasPublicationYear "2015" @default.
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