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• W4233407637 abstract "Abstract The reaction of 2‐siloxycyclo‐1,3‐dienes with E ‐vinyldiazoacetates in the presence of the bulky chiral dirhodium tetracarboxylate catalyst, Rh 2 ( R ‐ p ‐PhTPCP) 4 results in an enantioselective [4+2] cycloaddition, in which three new stereogenic centers are formed. The [4+2] cycloadducts are generated as single diastereomers with high enantiocontrol (95–98 % ee ). When the diene contains an additional stereogenic center, effective kinetic resolution can be achieved." @default.
• W4233407637 created "2022-05-12" @default.
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• W4233407637 date "2020-02-11" @default.
• W4233407637 modified "2023-10-16" @default.
• W4233407637 title "Rhodium‐Catalyzed Enantioselective [4+2] Cycloadditions of Vinylcarbenes with Dienes" @default.
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• W4233407637 doi "https://doi.org/10.1002/ange.201914354" @default.
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