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- W4233653864 abstract "1-Fluoro-4-hydroxy-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate) (Accufluor™ NFTh) is confirmed as a highly effective reagent for introducing a fluorine atom into organic molecules across a phenyl-substituted carbon-carbon double bond. Quantitative and Markovnikov-type regioselective formation of vicinal fluoro-hydroxy, fluoro-methoxy or fluoro-acetoxy adducts was achieved when phenyl-substituted alkenes were treated with a MeCN solution of NFTh In the presence of water, methanol or acetic acid. The stereochemical course of fluoro-methoxylation reactions in the case of cyclic phenyl-substituted alkenes depends strongly on the structure of the alkene." @default.
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- W4233653864 date "1995-01-16" @default.
- W4233653864 modified "2023-10-09" @default.
- W4233653864 title "1-Fluoro-4-hydroxy-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate) as a New, Effective Reagent for Selective Fluorofunctionalisation of Alkenes Under Mild Reaction Conditions" @default.
- W4233653864 doi "https://doi.org/10.1016/0040-4039(95)01337-h" @default.
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