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- W4233676481 abstract "Polyisoprene was vulcanized by 2-bisbenzothiazole-2,2′-disulfide (MBTS)/sulfur and tetramethylthiuram disulfide (TMTD)/sulfur in the absence and presence of benzoic and stearic acids. It was found that the crosslink density of MBTS vulcanizates is halved by the addition of carboxylic acids and this can be explained in terms of the attack of the acids on the accelerator polysulfides. TMTD polysulfides are more reactive toward polyisoprene than are MBTS polysulfides, and their addition to the polymer chain occurs before significant attack by the carboxylic acids can reduce the polysulfide concentration. Consequently, the acids have little effect on the crosslink density of TMTD vulcanizates. © 1999 John Wiley & Sons, Inc. J Appl Polym Sci 72: 1007–1012, 1999" @default.
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- W4233676481 date "1999-05-23" @default.
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- W4233676481 title "Effect of carboxylic acids on 2-bisbenzothiazole-2,2?-disulfide- and tetramethylthiuram disulfide-accelerated sulfur vulcanization. II. Vulcanization of polyisoprene in the absence of ZnO" @default.
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- W4233676481 doi "https://doi.org/10.1002/(sici)1097-4628(19990523)72:8<1007::aid-app4>3.0.co;2-w" @default.
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