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- W4233726943 abstract "The rhodium-catalyzed asymmetric N-selective coupling of pyrazole derivatives with terminal allenes gives access to enantioenriched secondary and tertiary allylic pyrazoles, which can be employed for the synthesis of medicinally important targets. The reaction tolerates a large variety of functional groups and labelling experiments gave insights into the reaction mechanism. This new methodology was further applied in a highly efficient synthesis of JAK 1/2 inhibitor (R)-ruxolitinib." @default.
- W4233726943 created "2022-05-12" @default.
- W4233726943 creator A5067624195 @default.
- W4233726943 creator A5070891497 @default.
- W4233726943 creator A5077100455 @default.
- W4233726943 date "2015-04-29" @default.
- W4233726943 modified "2023-10-11" @default.
- W4233726943 title "Regio- and Enantioselective Synthesis of N-Substituted Pyrazoles by Rhodium-Catalyzed Asymmetric Addition to Allenes" @default.
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- W4233726943 doi "https://doi.org/10.1002/ange.201501758" @default.
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