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- W4233806789 abstract "The intramolecular hydrosilylation of (4-pentenyl)hydrosilanes with transition metal salt catalysts afforded five- and six-membered ring-closure products in high yields, with the former predominating. This has been rationalized in terms of a reaction scheme based on the Harrod—Chalk mechanism in which both Si-metal and C-metal bonds were involved. The seven-membered intermediate leading to the six-membered ring products is apparently less favorable than the six-membered intermediate. However, with dicobalt octacarbonyl, no ring closure occurred, and only izomerization was observed." @default.
- W4233806789 created "2022-05-12" @default.
- W4233806789 date "1984-10-01" @default.
- W4233806789 modified "2023-09-25" @default.
- W4233806789 title "Subject index of volume 26" @default.
- W4233806789 doi "https://doi.org/10.1016/0304-5102(84)85114-7" @default.
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