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- W4234003181 abstract "The surface of LaNi5 is highly sensitive to residual gases in a vacuum. However, compared with the heat transfer effect, this surface effect has often been ignored in the investigation of the hydriding kinetics of LaNi5 because it has been assumed that the fresh surfaces appear by pulverization of the alloy in each hydriding reaction and that these surface conditions might be maintained also in the course of the dehydriding reaction. However, this work demonstrates that the hydriding rate becomes markedly decreased when the evacuation period for dehydriding in a low vacuum of 10−2 mbar is extended in the cycling. The changes in the hydriding rate and the form of the hydriding curve can be interpreted as due to alteration of the surface as a result of contamination. The validities of the Johnson-Mehl-Avrami type of equation and other experimental equations proposed in this work are examined to express the hydriding behaviour." @default.
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- W4234003181 date "1991-01-01" @default.
- W4234003181 modified "2023-09-27" @default.
- W4234003181 title "Effect of surface contaminations on the hydriding behaviour of LaNi5" @default.
- W4234003181 doi "https://doi.org/10.1016/s0022-5088(06)80328-0" @default.
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