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• W4234092972 startingPage "1264" @default.
• W4234092972 abstract "Kinetische Energiebarrieren ganz unterschiedlichen Ursprungs behindern den katalytischen N2O/CO-Redoxzyklus mit [YAlO2]+.- oder [Y2O2]+.-Clustern als Vermittler (siehe Schema). Während die Oxidation mit N2O für [YAlO2]+. den Flaschenhals darstellt, ist diese Oxidation für [Y2O2]+. möglich, doch die Reduktion von [Y2O3]+. durch CO läuft nicht ab. Dies ist die Folge von „Dotierungs“-Effekten, die lokale Ladungs- und Spinverteilungen beeinflussen können." @default.
• W4234092972 created "2022-05-12" @default.
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• W4234092972 creator A5067992887 @default.
• W4234092972 date "2012-12-06" @default.
• W4234092972 modified "2023-10-18" @default.
• W4234092972 title "On the Origin of the Surprisingly Sluggish Redox Reaction of the N₂O/CO Couple Mediated by [Y₂O₂]^+.and [YAlO₂]^+.Cluster Ions in the Gas Phase" @default.
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• W4234092972 doi "https://doi.org/10.1002/ange.201208559" @default.
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