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- W4234093863 abstract "Abstract Pincer Pd II –isocyanide complexes are described that display intermolecular interactions and emissive 3 MMLCT excited states in aggregation state(s) at room temperature. The intermolecular Pd II −Pd II and ligand–ligand interactions drive these complexes to undergo supramolecular polymerization in a living manner. Comprehensive spectroscopic studies reveal a pathway with a kinetic trap that can be modulated by changing the counteranion and metal atom. The Pd II supramolecular assemblies comprise two different aggregation forms with only one to be emissive. DFT/TDDFT calculations lend support to the MMLCT absorption and emission of these pincer Pd II –isocyanide aggregates." @default.
- W4234093863 created "2022-05-12" @default.
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- W4234093863 date "2018-02-02" @default.
- W4234093863 modified "2023-10-16" @default.
- W4234093863 title "The Metal–Metal‐to‐Ligand Charge Transfer Excited State and Supramolecular Polymerization of Luminescent Pincer Pd<sup>II</sup>–Isocyanide Complexes" @default.
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- W4234093863 doi "https://doi.org/10.1002/ange.201712249" @default.
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