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• W4234197246 abstract "Abstract. Photolysis of dimethylsulfide (DMS), a secondary photochemical process mediated by chromophoric dissolved organic matter (CDOM), has previously been demonstrated to be an important loss term of DMS in the surface layer of warm seas and the Southern Ocean. The role of photolysis in regulating the DMS dynamics in the Arctic Ocean, however, remains obscure. This study for the first time determined the apparent quantum yield (AQY) spectra of DMS photooxidation in northern polar marine milieus covering the Baffin Bay in the eastern Canadian Arctic and the Mackenzie River estuary, Mackenzie Shelf and Canada Basin in the western Canadian Arctic. The DMS AQY was fairly invariant at salinities < 25 but rose rapidly with further increasing salinity, which is well defined by a three-parameter exponential decay equation with a constant intercept. Salinity can therefore be used as a quantitative indicator of the DMS AQY. The DMS AQY in the ultraviolet (UV) wavelengths was linearly and positively correlated with the spectral slope coefficient (275–295 nm) of the CDOM absorption spectrum, suggesting that marine CDOM photosensitizes the degradation of DMS more efficiently than does terrestrial CDOM. High concentrations of nitrate (~12 μmol L−1) in deep water samples boosted DMS photooxidation by 70–80%, due likely to radical chemistry of nitrate photolysis. Coupled optical-photochemical modeling, based on the obtained DMS AQY spectra, shows that UV-A (320–400 nm) accounted for 60–75% of the DMS photolysis in the sunlit surface layer and that photochemistry degraded DMS on an e-folding time from 9 to 100 d (mean: 29 d). The photooxidation term on average accounted for 21% of the DMS gross loss rate and was comparable to the atmospheric DMS ventilation rate estimated for the same geographic regions." @default.
• W4234197246 created "2022-05-12" @default.
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• W4234197246 date "2013-02-06" @default.
• W4234197246 modified "2023-10-16" @default.
• W4234197246 title "Photooxidation of dimethylsulfide (DMS) in the Canadian Arctic" @default.
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• W4234197246 doi "https://doi.org/10.5194/bgd-10-2093-2013" @default.
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