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- W4234219644 abstract "Würfelförmige Käfige: Die Alkinylimidocluster 2 entstehen bei der Reaktion von 1 mit endständigen Alkinen. Nach Dichtefunktionalrechnungen läuft dabei eine Zweielektronenreduktion des Ti3-Fragments ab. Der vorgeschlagene Mechanismus besteht aus einer konzertierten C-H-Aktivierung, die zu einem Alkinyltitankomplex führt, und einer anschließenden Alkinylwanderung an den apicalen Nitridoliganden (siehe Bild). [Ti]=Ti(η5-C5Me5); R=SiMe3, Ph. Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2001/2007/z604677_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article." @default.
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- W4234219644 date "2007-04-20" @default.
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- W4234219644 title "Addition of Terminal Alkynes to a Molecular Titanium–Zinc Nitride" @default.
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