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- W4234521402 abstract "This chapter introduces chemical kinetics and discusses the milestones and pitfalls in the development of chemical kinetics and the relationship between kinetics and thermodynamics. The concepts of chemical kinetics evolved relatively late in terms of the overall studies of reactions and reactivity. Most probably, the practical importance of such studies did not exist at the end of the eighteenth century, and it was only with the advent of the chemical industry at the beginning of the nineteenth century that chemists, rather late, needed to consider. One of the major difficulties in the development of chemical kinetics stemmed from the lack of mathematical preparation of chemists of that period. The relationship between the macroscopic world and the microscopic world of molecules has been discussed in the chapter. The scope of chemical kinetics spans the area from nuclear processes up to the behavior of large molecules. Current practice in chemical kinetics tries to identify the one particular elementary step that has a very large effect on the overall reaction rate. This elementary process is known as the rate-determining step of the reaction." @default.
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- W4234521402 date "2007-01-01" @default.
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- W4234521402 title "Introduction" @default.
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- W4234521402 doi "https://doi.org/10.1016/b978-044452186-6/50001-8" @default.
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