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- W4234818480 abstract "Abstract The lithium bis(imino)stannylenoid (NIPr) 2 Sn(Li)Cl ( 1 ; NIPr=bis(2,6‐di iso propylphenyl)imidazolin‐2‐imino) was prepared by the reaction of LiNIPr with 0.5 equiv of SnCl 2 ⋅diox (diox=1,4‐dioxane) and the ambiphilic character of the compound was demonstrated by investigations into its reactivity. Treatment of 1 with I 2 or MeI yielded the oxidative addition products (NIPr) 2 SnI 2 and (NIPr) 2 Sn(Me)I, respectively. In contrast, the reaction of 1 with one equivalent of Me 3 SiCl resulted in the formation of Me 3 SiNIPr and the chlorostannylene dimer [NIPrSnCl] 2 . Moreover, the substitution reaction of compound 1 with MeLi led to the formation of the methyl‐substituted stannate (NIPr) 2 Sn(Li)Me." @default.
- W4234818480 created "2022-05-12" @default.
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- W4234818480 date "2016-04-21" @default.
- W4234818480 modified "2023-09-30" @default.
- W4234818480 title "A Tin Analogue of Carbenoid: Isolation and Reactivity of a Lithium Bis(imidazolin-2-imino)stannylenoid" @default.
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- W4234818480 doi "https://doi.org/10.1002/ange.201602178" @default.
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