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- W4234910118 abstract "[7681-82-5] INa (MW 149.89) InChI = 1S/HI.Na/h1H;/q;+1/p-1 InChIKey = FVAUCKIRQBBSSJ-UHFFFAOYSA-M (source of iodide ion for nucleophilic displacement reactions in the preparation of alkyl iodides4-10 and aryl iodides11-13 from halides and sulfonates; in combination with Zn, reduces sulfonates;14, 15 converts vic-dihalides and vic-disulfonates to alkenes;16-20 dehalogenates α-halo ketones21-23 and α-bromo enones;27 converts acyl chlorides to acyl iodides;24 cleaves aryl methyl25, 26 and some dialkyl ethers;27-32 deoxygenates epoxides;31 in combination with TMSCl/MeCN, generates TMSI in situ;33-35 catalyzes phosphorylations;36 reduces ene dicarbonyl compounds;37 converts acetylenic ketones to vinyl iodides;38 in combination with TMSCl/MeCN/0.5 H2O, generates ‘anhydrous HI’40 with various co-reagents, reduces sulfoxides41-43 and N-oxides;43a,44, 45 with oxidizing agents, iodinates organoboranes,46 phenols,47, 48 and aromatic compounds49) Physical Data: mp 661 °C; bp 1304 °C; d 3.667 g cm−3. Solubility: very sol cold H2O (184 g/100 mL, 25 °C), hot H2O (302 g/100 mL, 100 °C), alcohol (42.57 g/100 mL, 25 °C), acetone (39.9 g/100 mL, 25 °C); sol glycerin.2 Also sol acetic acid, acetonitrile, DMF, DMSO, formic acid, HMPA, methyl ethyl ketone. Form Supplied in: white solid (crystalline, granular, or powder); widely available. Drying: can be dried under vacuum at 70 °C.3 Handling, Storage, and Precautions: deliquescent in moist air (gradually absorbs up to ca. 5% (0.5 mol) H2O in air), and upon long exposure to air will turn brown due to liberation of iodine; storage in a dry or inert atmosphere is recommended." @default.
- W4234910118 created "2022-05-12" @default.
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- W4234910118 date "2001-04-15" @default.
- W4234910118 modified "2023-10-16" @default.
- W4234910118 title "Sodium Iodide" @default.
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- W4234910118 doi "https://doi.org/10.1002/047084289x.rs087" @default.
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