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- W4234973622 abstract "Zweite Generation: Eine verbesserte Synthese des umgelagerten Diterpens Aplyviolen wird beschrieben. Der Schlüsselschritt ist die Addition eines tertiären Trialkylradikals, erzeugt durch photoredoxvermittelte Fragmentierung eines N-(Acyloxy)phthalimids, an α-Chlorpentenon (siehe Schema). Der Prozess liefert ein quartäres Stereozentrum und vereinigt dabei zwei Bausteine von erheblicher Komplexität. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article." @default.
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- W4234973622 date "2012-08-24" @default.
- W4234973622 modified "2023-10-18" @default.
- W4234973622 title "A Concise Synthesis of (−)-Aplyviolene Facilitated by a Strategic Tertiary Radical Conjugate Addition" @default.
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- W4234973622 doi "https://doi.org/10.1002/ange.201204977" @default.
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