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- W4235082288 abstract "The addition of a large excess of 1,2-cyclopentanediol to a 1:1 mixture of glutathione and CrVI at pH 7.5 stabilises the intermediate CrV species formed by the one-electron reduction of CrVI by glutathione. The isotropic EPR parameters (giso and Aiso) of the CrV species formed with both cis- and trans-1,2-cyclopentanediol correspond to those calculated for five-coordinate oxo-CrV complexes with four alcoholato donors [Cr(O)(1,2-cyclopentanediolato)2]−. The five-coordinate oxo-CrV species formed with both 1,2-cyclopentanediol isomers show very similar EPR superhyperfine patterns, but differ in their stability and the conditions required for their formation due to the different chelation ability of the cis- vs. trans-1,2-diolato moiety." @default.
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- W4235082288 date "2001-07-01" @default.
- W4235082288 modified "2023-10-16" @default.
- W4235082288 title "The EPR Pattern of [CrO(cis-1,2-cyclopentanediolato)2]− and [CrO(trans-1,2-cyclopentanediolato)2]−" @default.
- W4235082288 doi "https://doi.org/10.1002/1099-0682(200107)2001:7<1829::aid-ejic1829>3.3.co;2-9" @default.
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