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- W4235611208 abstract "Entropieeffekte tragen in hohem Maße zur Basizität von Lithiumamiden bei. Der negative ΔS-Wert der Reaktion (Alkyl) (methyl)amino-substituierter Lithiumamide wie 1 mit Triphenylmethan ist das Resultat der Immobilisierung von THF-Molekülen durch Komplexbildung. Der pK-Wert der konjugierten Base von 1 ist um 4.3 Einheiten niedriger als der von Me2NH." @default.
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- W4235611208 date "2000-05-02" @default.
- W4235611208 modified "2023-09-23" @default.
- W4235611208 title "Lithiumamide: Intra-Aggregat-Komplexierung von Lithium und Entropieabhängigkeit der Basizität" @default.
- W4235611208 doi "https://doi.org/10.1002/(sici)1521-3757(20000502)112:9<1707::aid-ange1707>3.3.co;2-0" @default.
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