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- W4235630927 abstract "Abstract The first binuclear Au I compounds containing bridging (CF 2 ) n chains ( n =4, 6, 8) and Au III metallaperfluorocyclopentanes have been obtained by photoinitiated reactions of LAuMe (L=PPh 3 , PMe 3 , PCy 3 , or IPr) with α,ω‐diiodoperfluorocarbons. Complexes LAu(CF 2 ) 4 AuL present an unusual looped structure stabilized by an aurophilic interaction for L=PMe 3 , PPh 3 , and PCy 3 . The study of their dynamic behaviour has provided new insights about the strength of aurophilic interactions in solution, allowing quantification of the energy of a single Au⋅⋅⋅Au interaction." @default.
- W4235630927 created "2022-05-12" @default.
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- W4235630927 date "2020-06-22" @default.
- W4235630927 modified "2023-10-14" @default.
- W4235630927 title "Gold Complexes with Difunctional Perfluoroalkyl Chains: Quantifying the Energy of Aurophilic Interactions in Flexible Open‐Chain Complexes" @default.
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- W4235630927 doi "https://doi.org/10.1002/ange.202006440" @default.
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