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- W4235884365 abstract "The preferential solvation of Cd2+, Zn2+ and Na+ ions in H2O+CH3OH and H2O+DMSO mixtures was studied on base of equilibrium potential measurements. The electrolyte used was 0.1 and 0.9 M NaClO4. The Cic and BBCr reference systems were compared in H2O+DMSO mixtures. The BBCr system seemed to be more satisfactory. From the equilibrium potentials referred to BBCr the values of the transfer energies of Cd2+, Zn2+ and Na+ ions from H2O to DMSO or to CH3OH were estimated. The transfer energies of Zn2+ and Cd2+ ions as functions of xDMSO decreased monotonically indicating the selective solvation by DMSO in the whole composition range. The limiting values of ΔGtr for pure DMSO were −45 kJ mol−1 and −58 kJ mol−1 for Zn2+ and Cd2+ ions, respectively. The effects were small in the case of Na+ ions and no unambiguous conclusions concerning its selective solvation in this system could be drawn. In H2O+CH3OH mixtures the effects of selective solvation were very small for all three cations up to XCH3OH=0.8." @default.
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- W4235884365 date "1978-07-25" @default.
- W4235884365 modified "2023-09-26" @default.
- W4235884365 title "Medium effects in the systems: Cd2+ OR Zn2+ in some water + organic solvent mixtures deduced from equilibrium potentials at amalgam electrodes" @default.
- W4235884365 doi "https://doi.org/10.1016/0368-1874(78)85022-9" @default.
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